Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

您目前所在的位置:首页 - 期刊简介 - 详细页面

中国有色金属学报

ZHONGGUO YOUSEJINSHU XUEBAO

第22卷    第11期    总第164期    2012年11月

[PDF全文下载]        [Flash在线阅读]

    

文章编号:1004-0609(2012)11-3129-06
微量Zn对高压电解电容器阳极铝箔比电容的影响
左  宏1, 2,刘春明1

(1. 东北大学 材料各向异性与织构教育部重点实验室,沈阳 110819;
2. 新疆众和股份有限公司,乌鲁木齐 830013
)

摘 要: 采用X射线衍射仪定量检测立方织构,采用二次离子质谱仪分析铝箔表层Zn元素分布,采用扫描电子显微镜观察腐蚀结构,研究Zn含量对高压电解电容器阳极铝箔腐蚀结构及比电容的影响。结果表明:当Zn含量由1.9×106(质量分数,下同)提高至2.0×105时,铝箔立方织构的体积分数仍可达到95%,Zn更多地富集于铝箔表面,导致腐蚀结构均匀,进而使阳极在520 V时的比电容由0.666 μF/cm2增加到0.689 μF/cm2

 

关键字: 电解电容器;高压铝箔;微量锌;比电容

Influence of trace Zn on specific capacitance of high voltage aluminum anode foil used in high voltage electrolytic capacitors
ZUO Hong1, 2, LIU Chun-ming1

1. Key Laboratory for Anisotropy and Texture of Materials, Ministry of Education,
Northeastern University, Shenyang 110819, China;
 2. Xinjiang Joinworld Co., Ltd., Urumqi 830013, China

Abstract:The influences of the Zn content on the corrosion structure as well as the specific capacitance of the aluminum anode foils used in high voltage electrolytic capacitors were investigated. The cube texture of the foils was characterized by X-ray diffractometer (XRD) quantitatively and the distribution of Zn in the foils was measured by secondary ion mass spectrometer (SIMS). The corrosion structure of the etched foils was characterized by scanning electron microscope (SEM). The results show that when the Zn content of the foils varies from 1.9×10−6 (mass fraction) to 2.0×10−5, the cubic texture maintains at 95% (volume fraction), the surface segregation of Zn significantly increases, the corrosion structure becomes more homogeneous and the specific capacitance of the anode foils measured at 520 V increases from 0.666 μF/cm2 to 0.689 μF/cm2.

 

Key words: electrolytic capacitor; high voltage aluminum foil; trace zinc; specific capacitance

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

主管:中国科学技术协会 主办:中国有色金属学会 承办:中南大学
湘ICP备09001153号 版权所有:《中国有色金属学报》编辑部
------------------------------------------------------------------------------------------
地 址:湖南省长沙市岳麓山中南大学内 邮编:410083
电 话:0731-88876765,88877197,88830410   传真:0731-88877197   电子邮箱:f_ysxb@163.com