Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 25    No. 4    April 2015

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Long-term corrosion behavior of HVOF sprayed FeCrSiBMn amorphous/nanocrystalline coating
Yu-jiao QIN, Yu-ping WU, Jian-feng ZHANG, Wen-min GUO, Sheng HONG, Li-yan CHEN

Institute of Metals and Protection, College of Mechanics and Materials, Hohai University, Nanjing 210098, China

Abstract:A FeCrSiBMn amorphous/nanocrystalline coating with 700 μm in thickness and 0.65% in porosity, was prepared by high velocity oxygen fuel (HVOF) spraying process. The long-term corrosion behavior of the FeCrSiBMn coating was evaluated by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) tests in a 3.5% NaCl solution with a hard chromium coating as a reference. The FeCrSiBMn coating exhibited higher corrosion potential and lower corrosion current density than the hard chromium coating. The pore resistance (Rp) and charge transfer resistance (Rct) of FeCrSiBMn coating were higher than those of the hard chromium coating. In addition, after immersion in the NaCl solution for 28 d, only small pores in the FeCrSiBMn coating were observed. All the results indicated that the FeCrSiBMn coating held superior corrosion resistance to the hard chromium coating. This could be attributed to the dense structure, low porosity and amorphous/nanocrystalline phases of the FeCrSiBMn coating.

 

Key words: HVOF spraying; coating; Fe-based amorphous/nanocrystalline; corrosion resistance

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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