Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 28    No. 3    March 2018

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Phase equilibria in Ti-Ni-Pt ternary system
Yue ZHONG, Yue SUN, Hua-shan LIU, Ge-mei CAI, Zhan-peng JIN

School of Materials Science and Engineering, Central South University, Changsha 410083, China

Abstract:Phase equilibria in Ti-Ni-Pt ternary system have been experimentally determined through diffusion triple technique combined with alloy samples approach. Assisted with electron probe microanalysis (EPMA) and X-ray diffraction (XRD) techniques, isothermal sections at 1073 and 1173 K of this system were constructed and existence of ternary phase Ti2(Ni,Pt)3 was confirmed. In addition, binary compounds Ti3Pt5 and TiPt3- were found to be stable at 1073 and 1173 K, and remarkable ternary solubility in some binary compounds was detected, e.g., solubility of Pt in TiNi can be up to about 36% (molar fraction) at 1073 K and 40% (molar fraction) at 1173 K. Furthermore, a ternary invariant transition reaction TiNi3+Ti3Pt5→Ti2(Ni,Pt)3+TiPt3+ at a temperature between 1073 and 1173 K was deduced.

 

Key words: Ti-Ni-Pt ternary system; phase equilibrium; diffusion triple; solubility

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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